Each app has its own easily accessed setting menu. You shouldnt really need to use the main settings app very often anyway because most important things you would have on the home screen or notification pulldown, a feature iOS doesnt even have at all, yet (they did copy Android for iOS7).
Google account is the play account, which is your gmail account, you can ignore the Samsung account. If you have had an Android before once you sign in to google everything else falls into place automatically.
Dont you have to login to multiple accounts on iOS, if for example you have twitter, dropbox, etc?
The browsers give you choice, but use chrome. Why more than one? Because one isnt enough to cover all standards. Safari doesnt cover everything either.
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