I have the exact same problem in my 190 that is being recommissioned.
It was working fine then a couple of days later pedal to the floor, as the car had been parked for a number of years I was expecting a seal to pop somewhere or a corroded brake pipe but no leaks and certainly no loss of fluid.
I haven't yet explored the possibility of a brake valve failing if there is one, if not then the master it must be.
Check the plastic pipe from the brake servo as these tend to break through age or if its come apart.
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