Wireless networking in vista for one.
By XP SP2 Wireless networking was simple to use and reliable.
With Vista, I have had a number of problems.
Then we have the display drivers for Intel crashing repeatedly.
I seem to do the technical support for my family running windows PCs and by far the most reliable are on XP. Of course IMO they would be better on OS X but unfortunately, mum doesn't like Macs
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