open the command prompt on each PC but clicking on start and run and typing CMD into the bar. Click OK
When the prompt opens type ipconfig and jot down the ip address.
It should be something like 192.168.x.x
Once you have the numbers, ping them. On the command prompt again, ping the other machine.
EG. If the other machine was 192.168.2.3 you would type (on the other PC) ping 192.168.2.3. Repeat the process vice versa on the other machine.
Let us know what it says.
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